Improving the color yield of ink-jet printing on cationized cotton

This study examines the performance of digital ink-jet printing on cationized cotton treated with polyepichlorohydrin-dimethylamine (PECH-amine). The results show that the color yield of ink-jet printing with reactive inks on cationic modified cotton is much greater than that on untreated cotton. The effect on the increase of color yield by cationic modification is greater than that by preparation with alkali, urea, and thickener. The reason for this is that introducing positively charged sites increases dye uptake and dye fixation on cationized cotton. The results also show that cationic modification with PECH-amine decreases the rub fastness but increases the wash fastness of the treated cotton.

Conducting nylon, cotton and wool yarns by continuous vapor polymerization of pyrrole

Conductive textile yarns were prepared by a continuous vapor polymerization method; the application of polypyrrole by the continuous vapor polymerization method used is designed for the easy adaptation into industrial procedures. The resultant conductive yarns were examined by longitudinal and cross-sectional views, clearly showing the varying levels of penetration of the polymer into the yarn structure. It was found that for wool the optimum specific resistance was achieved by using the 400 TPM yarn with a FeCl3 solution concentration of 80 g/L FeCl3 to produce 1.69 Ω g/cm2. For cotton yarn, the optimum specific resistance of 1.53 Ω g/cm2 was obtained with 80 g/L of a FeCl3 solution.

Staying healthy : the case of cotton and cane growers in Australia

Farmers and fishers have always been exposed to the vagaries of climate and global economic forces. However, in recent years there has been an accumulation of factors which are having a particularly severe impact upon rural Australia. The global financial crisis has negatively affected commodity prices and the viability of some rural communities is under threat. There is evidence to suggest that climate change is already impacting adversely on many primary producers and their ability to farm using traditional methods. Furthermore, many parts of rural Australia are still experiencing the effects of long-term drought and associated problems. Together, these circumstances can rightly be conceived of as 'difficult times'. Key areas recently identified in a decline in mental health among farmers include: increasing isolation, ongoing drought, increased government regulations, and a widening of the schism between urban and rural Australians. While there is a body of literature on behaviour around illness in the context of the stress of ' difficult times', there is little on preventative behaviours in these circumstances. This chapter reports preliminary findings from an exploratory research projects that investigates the process by which farmers and fishers achieve and maintain good physical and mental health in the context of 'difficult times'. The research takes a multiple case study approach, with five Australian sites, each with a different industry base, representing communities undergoing 'difficult times'. This chapter focuses on two of the sites and data obtained from interviews with farmers in the cotton and sugar industries. It discusses the behavioural choices that they make to maintain good physical health and mental wellbeing. These include choices about nutrition, physical activity, social connections such as participation in community, social or farm-related groups, opportunities for relaxation and regular medical check-ups.

Reclaiming spent liquor from cotton reactive dyebaths using nanofiltration membrane for possible reuse of water and salt

During dyeing, salts are placed in a dyebath to aid the fixation of various dyes on to the fabric while bases are added to raise the pH from around neutral to pH 11. Afterwards, the used dyebath solution, called dyebath spent liquor, is discharged with almost all the salts and bases added as well as unfixed dyes. Consequently, a lot of raw materials are lost in the waste stream ending up in the environment as pollutants. In this study, possibilities of reusing water and salts of dyebathes were investigated, using a nanofiltration membrane. When the salt concentration in the spent liquor was increased from 10 to 80 g/L, the salt rejection by membrane was found to decrease initially; however, the salt rejection increased over the time, which was not expected. The aggregation of dye was also studied and found to decrease in the concentrate when the salt concentration was increased. This may be due to the aggregation of salt in the concentrate, which explains the increase in salt rejection. This information is useful for the textile industry in evaluating the treated water quality for the purpose of reuse.

Photoreactive azido-containing silica nanoparticle/polycation multilayers : durable superhydrophobic coating on cotton fabrics

In this study, we report the functionalization of silica nanoparticles with highly photoreactive phenyl azido groups and their utility as a negatively charged building block for layer-by-layer (LbL) electrostatic assembly to produce a stable silica nanoparticle coating. Azido-terminated silica nanoparticles were prepared by the functionalization of bare silica nanoparticles with 3-aminopropyltrimethoxysilane followed by the reaction with 4-azidobenzoic acid. The azido functionalization was confirmed by FTIR and XPS. Poly(allylamine hydrochloride) was also grafted with phenyl azido groups and used as photoreactive polycations for LbL assembly. For the photoreactive silica nanoparticle/polycation multilayers, UV irradiation can induce the covalent cross-linking within the multilayers as well as the anchoring of the multilayer film onto the organic substrate, through azido photochemical reactions including C–H insertion/abstraction reactions with surrounding molecules and dimerization of azido groups. Our results show that the stability of the silica nanoparticle/polycation multilayer film was greatly improved after UV irradiation. Combined with a fluoroalkylsilane post-treatment, the photoreactive LbL multilayers were used as a coating for superhydrophobic modification of cotton fabrics. Herein the LbL assembly method enables us to tailor the number of the coated silica nanoparticles through the assembly cycles. The superhydrophobicity of cotton fabrics was durable against acids, bases, and organic solvents, as well as repeated machine wash. Because of the unique azido photochemistry, the approach used here to anchor silica nanoparticles is applicable to almost any organic substrate.

Improving fiber trapping with a contact surface during the ring twisting of two cotton yarns

In this study, a geometrical model was introduced to improve the hair trapping via a surface contacting the yarn-twisting triangle during ring twisting of two single yarns. The fiber-trapping improvement with the contact surface was analyzed theoretically. Then, single Ne 80 ring cotton yarns were used to produce two-ply yarns under different ring-twisting conditions, namely conventional twisting, dry twisting of yarns with a plane surface, wet twisting of yarns with a plane surface, dry twisting of yarns with a grooved surface, and wet twisting of yarns with a grooved surface. Plied yarn properties, including yarn hairiness, strength, and irregularity, were tested. The Student Newman Keuls (SNK) test and variation analysis were also carried out in the SPSS program to study the effect of different contact surfaces on related yarn properties; the significance level was 0.05 for the SNK test and variation analysis. The hairiness of plied yarns was significantly reduced when twisting with the plane or grooved surface, especially for the wet twisting cases. This corresponds well with our model on improving fiber trapping.

Coloration of cotton fibers with anisotropic silver nanoparticles

Anisotropic silver nanoparticles were assembled on cotton fibers to realize the coloration of cotton. The assembly of silver nanoparticles on fibers was achieved by linking of poly(diallyldimethylammonium chloride) (PDDA) at room temperature. The silver nanoparticle treated cotton showed different colors because of localized surface plasmon resonance (LSPR) property of silver nanoparticles. The coloration was completed through electrostatic interaction between the PDDA treated cotton surface and the anisotropic silver nanoparticles in the reaction system. Scanning electron microscopy (SEM) characterization demonstrated that the morphologies of silver nanoparticles remained unchanged during the coloration process, so the treated cotton inherited the LSPR optical features of silver nanoparticles. Moreover, the cotton colorated with silver nanoparticles showed reasonably good color fastness to washing, which will facilitate the practical application of this coloration process.

Cooling effect of MWCNT-containing composite coatings on cotton fabrics

Multiwalled carbon nanotubes (MWCNTs) were dispersed in an aqueous solution of epichlohydrin based resin with the aid of a surfactant. The MWCNT-resin solutions were applied onto cotton fabrics to form a thin coating with different MWCNT contents (0, 11.1, 20.0, 33.3, and 50%). The thermal conductivity of the fabrics was measured based on the Newton’s law of cooling. The coating containing 50% MWCNTs showed 151% increase in the thermal conductivity. Infrared thermography was used to characterize the heating/cooling behavior of the fabrics. On contact with a 50°C hot surface, coated fabric that had 50% MWCNTs in the coating layer showed a 3.9°C lower equilibrium surface temperature than the untreated fabric. The cooling rate increased with increasing the MWCNT content within the coating layer. Such an effective cooling performance was attributed to the increased thermal conductivity and surface emissivity of the MWCNT-containing coating layer. The coating showed little influence on water contact angle of the coated fabrics, but slightly decreased the air permeability.